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11.
Four Haynesville Shale and four Bossier Shale samples were investigated using a combination of Scanning Electron Microscopy (SEM) and Broad Ion Beam (BIB) polishing. This approach enables the microstructure and porosity to be studied down to the mesopore size (<50 nm) in representative areas at the scale of the BIB cross-sections. The samples vary in mineralogy, grain size and TOC and the maturity ranges from 2.42 to 2.58 VRr in the Haynesville Shale to 1.79–2.26 VRr in the Bossier Shale. This variety within the samples enabled us to study controls on the porosity distribution in these shales. Visible pores exist as intraparticle pores mainly in carbonate grains and pyrite framboids and as interparticle pores, mainly in the clay-rich matrix. Pores in organic matter show a characteristic porosity with respect to the type of organic matter, which mainly consists of mixtures of amorphous organic matter and minerals, organic laminae and discrete macerals. A clear positive trend of organic-matter porosity with maturity was found. Pore sizes are power law distributed in the range of 4.4 μm to at least 36 nm in equivalent diameter. The differences in power law exponents suggest that a more grain supported, coarse-grained matrix may prevent pores from mechanical compaction. Porosities measured in the BIB cross-sections were significantly lower in comparison to porosities obtained by Mercury Intrusion Porosimetry (MIP). This difference is mainly attributed to the different resolution achieved with BIB-SEM and MIP and type of pore network. Extrapolation of pore size distributions (PSDs) enables the BIB-SEM porosity to be estimated down to the resolution of the MIP and thus to upscale microstructural observation at the confined space of the BIB-SEM method to bulk porosity measurement. These inferred porosities are in good agreement with the MIP determined porosities, which underpins the assumption that pores segmented in BIB-SEM mosaics are representative of the MIP methodology. 相似文献
12.
13.
Geometric characteristics and evolution of a tidal channel network in experimental setting 总被引:3,自引:0,他引:3
This paper reports on a laboratory study that aims to reproduce a tidal channel network, in order to enhance the understanding of the morphodynamic evolution of the channel characteristics as the network expands and finally reaches equilibrium. A high‐resolution laser system scanned the bed topography at different time steps creating multiple digital elevation models of the channel network. Two hundred and seventy individual channel segments are analyzed and cross‐correlated in terms of their width, depth and length. The laboratory results show positive linear correlations between depth and width as well as between length and width of channel segments of the network configuration at final equilibrium. In a downstream direction, channels appear to widen more than they deepen, indirectly a sign that discharge has a stronger control on channel width than on depth. In contrast to fluvial drainage networks that commonly display fractal and scale‐invariant behavior, the geometric properties of the experimental tidal creek network shows scale dependence. Channel attributes exhibit consistent patterns of exponentially decreasing abundance, with increasing creek length, depth and width. The nature of the observed exponential distributions within creek attributes (width, depth, length) allows for statistical predictability of relative creek attribute dimensions downstream and through time. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
14.
15.
Characteristics of high arsenic groundwater in Hetao Basin,
Inner Mongolia, northern China 总被引:2,自引:0,他引:2
It is well known that the Hetao Basin is one of the most seriously arsenic-affected groundwater areas in China. In order to understand the characteristics of high arsenic(As) groundwater in the Basin, a brief overview of arsenic in groundwater follows. High arsenic in the Basin commonly occurs in shallow groundwater and the total arsenic concentrations range from 0.58 to 572 μg/L(average 99.73 μg/L), exceeding the maximum mandated value of 10 μg/L for drinking water in China; As(Ш) is the predominant species. The regional distribution pattern of arsenic in the groundwater increases from south/southeast to north/northwest. Hangjinhouqi and Wuyuan counties are considered as the most seriously affected areas, with high incidences of endemic arsenicosic diseases in the Hetao Basin. High groundwater arsenic correlates with the increase of well depth. Previous studies proposed that groundwater arsenic in the Basin is mainly originated from desorption of some natural solid materials in the sediments, under reducing condition. Generally, reducing condition is believed to be the primary factor for arsenic releasing from the sediment to groundwater in the region. Under inorganic or bacterial processes, Fe2O3 changes to Fe S and arsenic adsorbed to Fe(OH)3 dissolves into groundwater, and As(V) is reduced to As(Ш). Besides, reducing environments, groundwater hydraulic gradients, organic matter, p H, evapotranspiration, and soil texture are presumed to be the predominant factors that control arsenic mobilization. 相似文献
16.
Abstract The vertical profiles of streamwise velocities are computed on flood plains vegetated with trees. The calculations were made based on a newly developed one-dimensional model, taking into account the relevant forces acting on the volumetric element surrounding the considered vegetation elements. A modified mixing length concept was used in the model. An important by-product of the model is the method for evaluating the friction velocities, and consequently bed shear stresses, in a vegetated channel. The model results were compared with the relevant experimental results obtained in a laboratory flume in which flood plains were covered by simulated vegetation. 相似文献
17.
A consistent approach to the frequency analysis of hydrologic data in arid and semiarid regions, i.e. the data series containing several zero values (e.g. monthly precipitation in dry seasons, annual peak flow discharges, etc.), requires using discontinuous probability distribution functions. Such an approach has received relatively limited attention. Along the lines of physically based models, the extensions of the Muskingum‐based models to three parameter forms are considered. Using 44 peak flow series from the USGS data bank, the fitting ability of four three‐parameter models was investigated: (1) the Dirac delta combined with Gamma distribution; (2) the Dirac delta combined with two‐parameter generalized Pareto distribution; (3) the Dirac delta combined with two‐parameter Weibull (DWe) distribution; (4) the kinematic diffusion with one additional parameter that controls the probability of the zero event (KD3). The goodness of fit of the models was assessed and compared both by evaluation of discrepancies between the results of both estimation methods (i.e. the method of moments (MOM) and the maximum likelihood method (MLM)) and using the log of likelihood function as a criterion. In most cases, the DWe distribution with MLM‐estimated parameters showed the best fit of all the three‐parameter models. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
18.
基于GIS的震害空间分布图集的设计与编制 总被引:2,自引:0,他引:2
快速地生成震害分布预测图,对提高减灾救灾能力有着重要意义。本研究采用3S(地理信息系统—G IS、全球定位系统—GPS和遥感—RS)技术,设计了一套全方位、多角度、综合自然环境、社会经济和人文要素的震害空间分布图集。本文将G IS强大的空间分析和数据管理能力与GPS、RS和地震科学相结合,从设计思想、图集内容、表现形式等方面介绍了专题图集的设计与编制。经过多次地震应急演练,该图集在制图规范化和出图速度方面有了较大的改善,能为应急指挥和辅助决策提供有力的技术保障。 相似文献
19.
Víctor Leiva Antonio Sanhueza José M. Angulo 《Stochastic Environmental Research and Risk Assessment (SERRA)》2009,23(3):299-307
In this article, we develop a new model based on the Birnbaum-Saunders distribution that results to be both useful and practical
for environmental sciences. The density, distribution and hazard functions, moments and properties of this new model are presented.
A graphical analysis of the density is also provided. Furthermore, we estimate parameters, propose asymptotic inference and
discuss influence diagnostics by using likelihood methods for the new distribution. An illustrative example with real data
related to water quality indicates the adequacy on the new distribution. 相似文献
20.
近50年来云南气候带的变化特征 总被引:7,自引:1,他引:6
利用云南115个气象观测站1961-2006年逐日平均气温求算稳定≥10℃积温.并对积温资料按年代建立与海拔、经度和纬度相关联的小网格推算模型.再应用地理信息系统(GIS)订正到0.01×0.01°网格点,得出云南5个不同年代细网格积温分布.在此基础上划分7个气候带地理分布图,并分别计算其面积.据此分析,近50年来云南气候带总体上呈现热带亚热带范围扩大、温带范围减少的变化趋势,其中以北热带增加最明显,增幅达到90.2%;而南温带减少最明显,减幅为12.5%.在年代际变化上,1960-1970年表现出热带亚热带范围减小,温带范围增加;从1970年后则呈现热带亚热带范围快速增加,温带范围减小的趋势.而1990年代以来是气候带变化最大的时期. 相似文献